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氧气,氢气,氮气等气体不同,沼气其实是一种混合气体,其主要组成成分包括甲烷,二氧化碳,硫化氢,水蒸气等,不同方式产生的沼气中各成分的比例会有所不同,但主要成分都是甲烷即CH4,因此,沼气可燃烧,并且可以作为一种可再生能源使用。
Oxygen, hydrogen, nitrogen and other gases are different. Biogas is actually a mixed gas, and its main components include methane, carbon dioxide, hydrogen sulfide, water vapor, etc. The proportion of each component in biogas produced by different methods may vary, but the main component is methane, which is CH4. Therefore, biogas can be burned and can be used as a renewable energy source.
在沼气的这些组成成分中,硫化氢气体即H2S,本身具有臭味,而且对人体有害,并且能溶于水形成氢硫酸,对沼气设备也会产生腐蚀性,所以在利用沼气或者进行燃烧排放前需要利用相关设备尽可能地去除硫化氢。这一步处理就被称为沼气脱硫。
Among these components of biogas, hydrogen sulfide gas, also known as H2S, has a foul odor and is harmful to human health. It can dissolve in water to form hydrosulfuric acid, which can also cause corrosion to biogas equipment. Therefore, before using biogas or conducting combustion emissions, it is necessary to use relevant equipment to remove hydrogen sulfide as much as possible. This step of treatment is called biogas desulfurization.
目前可以实现工业化运行的脱硫方法主要有三种,分别是干法脱硫,湿法脱硫和生物脱硫:
There are currently three main desulfurization methods that can achieve industrial operation, namely dry desulfurization, wet desulfurization, and biological desulfurization:
1、干法脱硫常用于低硫量沼气的处理,尤其适合于中小型的沼气工程,比如养殖场沼气池、垃圾填埋场填埋气处理、污水处理厂曝气池的沼气处理等,因为其设备结构结构简单,维护方便,几乎不需要人员进行操作,只需要定期对脱硫剂进行再生和更换即可。目前市面上干法脱硫的脱硫剂一般采用氧化铁颗粒,因为其成本较低,而且再生操作简单。其他脱硫剂如氧化锌、活性炭等因为无法再生,脱硫后只能进行废弃处理,不仅容易造成环境问题,还会提高脱硫成本。
1. Dry desulfurization is commonly used for the treatment of low sulfur biogas, especially suitable for small and medium-sized biogas projects, such as biogas tanks in breeding farms, landfill gas treatment in garbage landfills, and biogas treatment in aeration tanks in sewage treatment plants. Due to its simple equipment structure, easy maintenance, and almost no need for professional personnel to operate, it only requires regular regeneration and replacement of desulfurizers. At present, the desulfurizer for dry desulfurization on the market generally uses iron oxide particles because of their lower cost and simple regeneration operation. Other desulfurizers such as zinc oxide and activated carbon cannot be regenerated and can only be disposed of after desulfurization, which not only causes environmental problems but also increases desulfurization costs.
2、湿法脱硫是将沼气送入特定溶剂中去除H2S的过程,一般是适用石灰石或石灰的浆液作为脱硫剂,湿法脱硫的脱硫率一般大于90%,而且处理量大,适用于大型沼气工程。但是湿法脱硫的缺点也比较明显:初期的投资费用高、运行费用高、占地面积大、系统操作复杂需要专人维护,副产物——石膏和废水都比较难处理。
2. Wet desulfurization is the process of sending biogas into a specific solvent to remove H2S. Generally, limestone or lime slurry is used as a desulfurizer. The desulfurization rate of wet desulfurization is generally greater than 90%, and the processing capacity is large, making it suitable for large-scale biogas projects. However, the drawbacks of wet flue gas desulfurization are also quite obvious: high initial investment costs, high operating costs, large footprint, complex system operation requiring dedicated personnel to maintain, and difficult to treat by-products such as gypsum and wastewater.
3、生物脱硫又称生物催化脱硫(简称BDS),是一种新式的沼气脱硫方式,在常温常压条件下利用特定种类的细菌进行生物处理脱硫。生物脱硫技术包括生物过滤、生物吸附和生物滴滤法。这三个系统是开放的,它们的微生物种群会随着环境的变化而变化。在生物脱硫过程中,氧化硫污染物应通过生物还原生成硫化物或H2S,硫元素应通过生物氧化生成单质硫之后去除。
3. Biological desulfurization, also known as biocatalytic desulfurization (BDS), is a new type of biogas desulfurization method that utilizes specific types of bacteria for biological treatment and desulfurization under normal temperature and pressure conditions. Biological desulfurization technology includes biological filtration, biological adsorption, and biological drip filtration. These three systems are open, and their microbial populations will change with changes in the environment. In the process of biological desulfurization, sulfur oxide pollutants should be bioreduced to generate sulfides or H2S, and sulfur elements should be removed after generating elemental sulfur through biological oxidation.
通过自动化技术的应用,实现了金属板材加工的率和高精度。
Through the application of automation technology, high efficiency and precision in metal sheet metal processing have been achieved.
本文由沼气脱硫提供技术支持,更多的详细精彩内容请点击我们的网站 http://www.fcw-app.com我们将会全心全意为您提供满意的服务。
This article provides technical support for biogas desulfurization. For more detailed and exciting content, please click on our website http://www.fcw-app.com We will wholeheartedly provide you with satisfactory service.